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Intermediate carbene formation in the reaction of thioamides with phosphorus (III) derivatives: Quantum chemical investigation

โœ Scribed by Rozhenko, Alexander B.; Mykhaylychenko, Sergiy S.; Pikun, Nadiya V.; Shermolovich, Yuriy G.; Leszczynski, Jerzy


Book ID
121651893
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
631 KB
Volume
114
Category
Article
ISSN
0020-7608

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Formation of semiquinone radical in the
โœ Ravi Joshi; Tapan K. Ghanty; Tulsi Mukherjee ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 638 KB

Embelin, 2,5-dihydroxy-3-undecyl-1,4-benzoquinone, has two intra-molecular hydrogen bonds between the quinone and hydroquinone groups present on the same ring. Therefore, it is expected to produce semiquinone radical in the oxidation as well reduction reactions. To investigate this aspect, kinetics