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Intermediacy of iridodial in the biosynthesis of some iridoid glucosides

โœ Scribed by Hiroyuki Inouye; Shinichi Ueda; Shinichi Uesato


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
863 KB
Volume
16
Category
Article
ISSN
0031-9422

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## Abstract The kinetic measurements in the Flash Vacuum Thermolysis (FVT) of 3,5โ€Dimethylโ€ and 5โ€Methylโ€ 4โ€Nitroisoxazole confirm the already suggested intermediacy of the isomer 2Hโ€Azirine in the formation of 1โ€ Cyanoโ€1โ€Nitroacetone. Moreover, theoretical calculations of the stabilization energy