Abstract
Shear properties of laminates consisting of graphite fiber (Celion 6000, Celion 3000, and Tβ300) and several resins (epoxy, hot meltβbismaleimide, solvent bismaleimide, polyimide, and polystyrylpyridine (PSP)) were measured using the shortβbeam test. The interlaminar shear strength of epoxy composites was hightest. All other resin composites showed considerably lower shear properties. The shear strengths deereased with temperature, with the loss up to 100Β°C being more pronounced. The PSP composites did not show a loss in strength in the temperature range investigated (room temperature to 250Β°C). Boiling the composite samples in water for 24 h resuled in negligible reduction in shear strength in all cases. The interlaminar shear properties depended on the fiberresin interfacial bond, the wetting characteristics of the resin, and the resin meechanical properties. Attempts were made to determine to what extent each of these factors controlled the shear properties of the composites studies. Thus, the interfacial bond between the resin and the single fiber was determined. Results showed that the lower shear strength of polyimide, bisimides and PSP composites, as compared to epoxy resin composites, seemed to be due to their corresponding low interfacial bond strengths. The subsequent decrease in shear strength with temperature appeared to be directly correlated to the decrease in bond strength. The wettability of carbon fiber tow with all these resins was also determined. The small variations in wetting characteristics of the resin did not seem to justify the rather large differences in shearβstrength properties observed.