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Intergrowths of oxygen defect perovskite layers and SrO layers: Electron transport properties of the oxides: La2−xA1+xCu2O6−x/2+σ (A = Ca, Sr)

✍ Scribed by N. Nguyen; C. Michel; F. Studer; B. Raveau


Publisher
Elsevier Science
Year
1982
Weight
437 KB
Volume
7
Category
Article
ISSN
0390-6035

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✦ Synopsis


The conductivity, Seebeck effect and magnetic suscepUbfllty of the oxides La2-x A1 + x Cu2 O6-x/2 + 6 (A = Ca, Sr) have been mvestxgated These compounds which contain variable amounts of tnvalent copper are characterized by a hole conduction A progresswe evoluhon of the electron transport properties from a semi-conductor to a semi-metal is observed according to the amount of Cu 3+ These properties are interpreted m terms of a Mott band model The influence of the oxygen pressure during the electrical measurements ~s also considered