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Interfacial tension between microemulsion and excess dispersed phases

✍ Scribed by Paul D.I. Fletcher


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
363 KB
Volume
141
Category
Article
ISSN
0009-2614

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✦ Synopsis


Two-phase systems consisting of water-in-oil (W/O) microemulsions in equilibrium with excess water and oil-in-water (O/W) microemulsions in equilibrium with excess oil have been prepared using the surfactant sodium bis( 2-ethylhexyl)sulphosuccinate (AOT) without cosurfactant. The interfacial tension of the planar interface separating the phases for the W/O case is only weakly dependent upon the volume fraction ofdroplets in the microemulsion phase whereas for the O/W case, the microemulsion droplet size increases and the tension drops as the dispersed volume fraction is increased.


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Phase behaviour of microemulsions: Deriv
✍ E. Ruckenstein πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 421 KB

An equation is proposed Ior the intaIacial tenston CJ between a microcmulsion and the excess dlspcrscd phase. relaring this quantity to other measurable quantities such as the radms of lhe globules r and their volume kaction 9. Thrs eqwtion is obtained by subtracting rrom tie interracial tension y a