Interfacial Nanochemistry: Molecular Science and Engineering at Liquid-Liquid Interfaces (Nanostructure Science and Technology)

✍ Scribed by Hitoshi Watarai, Norio Teramae, Tsuguo Sawada

• Year: 2005
• Tongue: English
• Leaves: 328
• Edition: 1
• Category: Library

✦ Synopsis

This is the first book to feature interfacial nanochemistry of liquid/liquid interfaces, which is a new boundary field between analytical chemistry, colloid and surface chemistry, electrochemistry, laser spectroscopy, separation engineering, and interfacial organic synthesis. The liquid/liquid interface is a very general subject of interest both to pure and industrial chemists, especially those engaged in research on solvent extraction of metal ion and organic compounds, interfacial synthesis, and micro-scale analysis. This book will give them deep insight into the nature of the liquid/liquid interface and what kind of reactions can take place there.

✦ Table of Contents

Contents......Page 11
1.1 Introduction......Page 15
1.2 SHG theory......Page 16
1.3 Experimental techniques......Page 20
1.5 Adsorption of para-nitrophenol......Page 21
1.6 Flow cell experiments......Page 24
1.7 Dye molecules at the dodecane/water interface......Page 27
1.8 Electrochemical liquid/liquid interfaces......Page 29
1.9 Chiral molecules at liquid/liquid interfaces......Page 30
1.10 SHG from micelles and liposomes......Page 31
1.11 Concluding remarks......Page 33
2.1 Introduction......Page 38
2.2 Theoretical considerations of VSFS......Page 39
2.3 Experimental considerations......Page 49
2.4 Applications......Page 50
2.5 Summary and future directions......Page 69
3.1 Introduction......Page 72
3.2 Time-resolved quasi-elastic laser scattering method......Page 73
3.3 A phase transfer catalytic reaction at a liquid/liquid interface......Page 77
3.4 A chemical oscillation induced by anionic surfactant at a w/nb interface......Page 82
3.5 Concluding remarks......Page 87
4.1 Introduction......Page 90
4.2 Types of colloidal forces......Page 92
4.3 Atomic force microscopy at rigid interfaces......Page 95
4.4 Force measurements at liquid interfaces......Page 97
4.5 General behaviour of forces at liquid interfaces......Page 102
4.6 Concluding remarks......Page 105
5.1 Introduction......Page 109
5.2 Molecular theory of fluid phase equilibria......Page 112
5.3 Microscopic description of liquid/liquid and liquid/vapour interfaces......Page 115
6.1 Introduction......Page 138
6.2 Voltammogram for ion transfer at the w/o interface......Page 139
6.3 Voltammogram for electron transfer at the w/o interface......Page 142
6.4 Ion transfer coupled with electron transfer at the w/o interface......Page 143
6.5 Process of ion transport through a membrane......Page 149
6.6 New types of membrane reactions mimicking biological processes......Page 152
6.7 Oscillation of membrane current or membrane potential......Page 156
6.8 Conclusion......Page 163
7.1 Introduction......Page 165
7.2 Theoretical background......Page 166
7.3 Experimental features of electrochemical instability in electrochemical transfer of ionic surfactant across the liquid/liquid interface......Page 175
7.4 Conclusions......Page 178
8.1 Introduction......Page 181
8.2 Electron transfer at the polarizable o/w interface......Page 182
8.3 New methodologies......Page 185
8.4 Reaction mechanisms......Page 187
8.5 Concluding remarks......Page 195
9.1 Introduction......Page 199
9.2 Manipulation, electrochemistry and spectroscopy of single microdroplets......Page 200
9.3 Microdroplet size effect on mass transfer and reaction rate......Page 202
9.4 Simple ion-pair extraction in a single micro-oil-droplet/water system......Page 204
9.5 Ion-pair extraction of an anionic surfactant with a cationic dye......Page 208
9.6 Concluding remarks......Page 213
10.1 Introduction......Page 215
10.2 Interfacial diffusion dynamics......Page 217
10.3 Interfacial catalysis......Page 224
10.4 Interfacial aggregation......Page 233
10.5 Concluding remarks......Page 238
11.1 Introduction......Page 242
11.2 Hydrogen-bond-mediated anion recognition at L/L interfaces......Page 243
11.3 Molecular recognition at L/L interfaces as studied by second harmonic generation spectroscopy......Page 248
11.4 Concluding remarks......Page 255
12.1 Introduction......Page 258
12.2 Theoretical and experimental backgrounds......Page 259
12.3 TIR fluorescence dynamic anisotropy at a liquid/liquid interface......Page 262
12.4 Excitation energy transfer and its dynamics at a water/oil interface......Page 266
12.5 Structures at a liquid/liquid interface......Page 268
12.6 A relationship between interfacial structure and polarity at a liquid/liquid interface......Page 273
12.7 Photochemical observation of molecular recognition at a liquid/liquid interface......Page 275
12.8 Concluding remarks......Page 276
13.1 Introduction......Page 279
13.2 Surfactant-type Lewis acids for reactions in water......Page 281
13.3 Surfactant-type Brønsted acids for reactions in water......Page 286
13.4 Concluding remarks......Page 292
14.2 Reverse micellar protein extraction......Page 294
14.3 Extraction of DNA through liquid–liquid interfaces......Page 305
14.4 Concluding remarks......Page 309
A......Page 310
C......Page 311
D......Page 313
E......Page 315
H......Page 316
I......Page 317
L......Page 318
M......Page 319
P......Page 321
R......Page 323
S......Page 324
T......Page 326
V......Page 327
Z......Page 328