This paper intends to analyze the influences of the interface and interface regions (see wording in Adamson, A. W., "Physical Chemistry of Surfaces," Wiley, New York, 1976), between two phases on the equilibrium course of the phases and to discuss the phase equilibrium theory by means of the theoret
Interface Layer Model of Physical Interface
β Scribed by Zhang Fu Tian
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 113 KB
- Volume
- 244
- Category
- Article
- ISSN
- 0021-9797
No coin nor oath required. For personal study only.
β¦ Synopsis
On the basis of investigations of the theory of surface phenomena, the interface layer model of physical interface is proposed in this paper. The concepts of respective interfacial tension and surface forces in the internal and external regions of two phases are proposed. Calculation equations for these parameters are deduced. Surface forces are discussed on the basis of the theory of intermolecular interactions. The contribution of the inductive forces to the surface energy is taken into account in the theoretical calculation. Results of the calculation show that the theoretical model proposed in this paper is reasonable.
π SIMILAR VOLUMES
The 'rheological model' of adhesion developed by Gent and Schultz significantly broadened the applicability of the thermodynamic model of adhesion by accounting not only for the thermodynamic energy of adhesion, but also for the irreversibly dissipated energy occurring during viscoelastic and plasti