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Interesting Behavior of α,β-Unsaturated Oximes in Intramolecular [4 + 2] Cycloaddition Reactions

✍ Scribed by François, David; Maden, Amy; Murray, William V.


Book ID
126205355
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
94 KB
Volume
6
Category
Article
ISSN
1523-7060

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📜 SIMILAR VOLUMES


Intramolecular [2 + 2] cycloaddition rea
✍ Yashwant S. Kulkarni; Beverly W. Burbaum; Barry B. Snider 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 270 KB

Treatment of a,P-unsaturated acid chlorides 5, 6, 14, 17, and 18 with NEt3 in toluene at reflux generates, stereo-and regiospecifically, the vinylketene which undergoes a facile intramolecular [2 + 21 cycloaddition.