Interconversions among alkoxyfluorophosphoranes: effect of differences in apicophilicity on the equilibrium distribution of substituents on five-coordinated phosphorus

A kinetic study of the alkaline hydrolys

A kinetic study of the alkaline hydrolysis of four-coordinated phosphorus (PIV) compounds. Impact of conformational transmission in the transiently formed five-coordinated (PV-TBP) intermediates on reaction rate and product distribution

✍ Leo H. Koole; Edith A. T. A. Olders; Marko Opresnik; Henk M. Buck 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 404 KB

## Abstract It can be shown that alkaline hydrolysis of four‐coordinated phosphorus (P^IV^) compounds is substantially accelerated if the trigonal‐bipyramidal (TBP) five‐coordinated phosphorus (P^V^) intermediate in the reaction can exhibit conformational transmission. With the compounds 5a‐c, it w