Interconversion between Polymeric and Monomeric Forms of Oxovanadium(IV) Complexes with Tetradentate Schiff Base Ligands Derived from (R,R)-2,4-Pentanediamine

Mechanochemical Reaction of Polymeric Ox

Mechanochemical Reaction of Polymeric Oxovanadium(IV) Complexes with Schiff Base Ligands Derived from 5-Nitrosalicylaldehyde and Diamines

✍ Masanobu Tsuchimoto; Gakuse Hoshina; Naoki Yoshioka; Hidenari Inoue; Kiyohiko Na 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 185 KB

Light brown [VO(5-NO 2 salen)] ' 2H 2 O (1; H 2 (5-NO 2 salen)‫؍‬N, N-di-5-nitrosalicylidene-1,2-ethanediamine) and orange [VO(5-NO 2 sal-meso-stien)] ' 0.5H 2 O (2; H 2 (5-NO 2 salmeso-stien) ‫؍‬ N,N-di-5-nitrosalicylidene-(R,S)(S,R)-1,2diphenyl-1,2-ethanediamine) which have linear chain structures