Intercomparison of NO, NO2and HNO3measurements with photochemical theory
β Scribed by Evans, W.F.J. ;Kerr, J.B. ;Wardle, D.I. ;McConnell, J.C. ;Ridley, B.A. ;Schiff, H.I.
- Book ID
- 127141488
- Publisher
- Informa UK (Taylor & Francis)
- Year
- 1976
- Weight
- 504 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0004-6973
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## Abstract The oxidation of copper, zinc and nickel by N~2~O~5~ led, respectively, to turquoiseβcoloured single crystals of (NO)Cu(NO~3~)~3~ [monoclinic, __P__2~1~/__m__, __Z__ = 2, __a__ = 465.90(5), __b__ = 1111.7(1), __c__ = 700.7(1) pm, __Ξ²__ = 100.70(2)Β°, __wR__~2~ = 0.0566], lightβyellow sin
Flowing and static gas-phase samples of HNO3 in 0 2 and N2 were analyzed by long-path ultraviolethisible (TJV/VIS) spectroscopy to reveal the presence of both NO2 and NO3, the concentrations of which were calculated using differential absorption cross sections. NO2 is produced predominantly by the h