## Abstract To calculate atomβatom interactions at high temperatures, one needs the electron densities of the interacting atoms. The present paper outlines an approach by which the temperatureβdependent electron densities of compressed atoms may be obtained. The approach suggested makes use of the
Interchange of hydrogen and oxygen atoms in o-nitrotoluene at high temperatures
β Scribed by Ellis K. Fields; Seymour Meyerson
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 135 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In a study of arylation by aromatic nitro compounds at high temperatures,1 we had, occasion to examine the reactions of o-nitrotoluene with benzene.
-A solution of 6.14 ml.
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Rates of reaction of atomic oxygen ('P) with straight chain alkanes (C&5) and fluoromethanes (CHP and CHF,) have been measured at temperatures above 850 K by a laser flash photolysis-shock-tube technique coupled with atomic resonance absorption spectrometry. Measured rate constants agreed well with
The kinetics of the reaction of 0 atoms with NO2 was investigated in the temperature range 199-357 K. The value of the rate constant can be expressed by k, = (5.21 kO.50) x lo-'\* exp [(202\*27)lT] cm3 s-' (3~ error). At temperatures below 230 K, the formation of equilibrium concentrations of N204 a