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Interchain Pressure Effect in Extensional Flows of Entangled Polymer Melts

✍ Scribed by Marrucci, Giuseppe; Ianniruberto, Giovanni

Book ID
126277088
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
103 KB
Volume
37
Category
Article
ISSN
0024-9297

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We present an extension of the Rouse-CCR tube model for linear entangled polymers, by incorporating interchain repulsive excluded-volume interactions, to interpret extensional viscosity data of narrow molecular weight distribution polystyrene melts in strong extensional flows. The expression for the