The heterogeneous oxidation of benzenethiol catalyzed by the dianionic bis(2-sulfanyl-2,2diphenylethanoxycarbonyl) dioxomolybdate (VI) complex intercalated into a Zn(II)-Al(III) layered double hydroxide (LDH) host have been investigated under aerobic conditions. The kinetics of the system has been a
โฆ LIBER โฆ
Intercalation of [MoVIO2(O2CC(S)Ph2)2]2- in a Zn(II)-Al(III) Layered Double Hydroxide Host: A Strategy for the Heterogeneous Catalysis of the Air Oxidation of Thiols
โ Scribed by Cervilla, Antonio; Corma, Avelino; Fornes, Vicente; Llopis, Elisa; Palanca, Pedro; Rey, Fernando; Ribera, Antonio
- Book ID
- 120441073
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 278 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0002-7863
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The heterogeneous reduction of nitrobenzene by thiophenol catalyzed by the dianionic bis(2-sulfanyl-2,2-diphenylethanoxycarbonyl) dioxomolybdate(VI) complex, [Mo VI O 2 (O 2 CC(S)(C 6 H 5 ) 2 ) 2 ] 2ฯช , intercalated into a Zn(II)-Al(III) layered double hydroxide host [Zn 3ฯชx Al x (OH) 6 ] xฯฉ , has b