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Intercalation of 7,8-dihydroxy-9,10-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene enantiomeric isomers with dinucleoside dimers: A basis for alkylation of the 2-amino group in guanine

✍ Scribed by Y. Nakata; D. Malhotra; A. J. Hopfinger; D. R. Bickers

Publisher: John Wiley and Sons
Year: 1983
Tongue: English
Weight: 302 KB
Volume: 72
Category: Article
ISSN: 0022-3549
DOI: 10.1002/jps.2600720722

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## Abstract The reaction of (±)‐7α,8β‐dihydroxy‐9β,10β‐epoxy‐7,8,9,10‐tetrahydrobenzo(__a__)pyrene (BP diol epoxide) with DNA, followed by enzymatic hydrolysis and LH 20 Sephadex column chromatography, yielded products containing a purine deoxyribonucleoside linked to a 7,8,9,10‐tetrahydrobenzo(__a