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Intercalated Polycarbonate/Clay Nanocomposites: Nanostructure Control and Foam Processing

✍ Scribed by Masaki Mitsunaga; Yasuhito Ito; Suprakas Sinha Ray; Masami Okamoto; Katsuhiko Hironaka


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
212 KB
Volume
288
Category
Article
ISSN
1438-7492

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✦ Synopsis


Abstract

Intercalated polycarbonate (PC)/clay nanocomposites (PCCN)s have been prepared successfully through the melt intercalation method in the presence of a compatibilizer. The internal structure and morphology of the PCCNs has been established by using wide‐angle X‐ray diffraction (WAXD) analyses and transmission electron microscopic (TEM) observations. The morphology of these nanocomposites and degradation of the PC matrix after nanocomposites preparation can be controlled by varying surfactants used for the modification of clay and compatibilizer. The intercalated PCCNs exhibited remarkable improvements of mechanical properties when compared with PC without clay. We also discuss foam processing of one representative PCCN using supercritical CO~2~ as a foaming agent.

TEM bright field image of intercalated polycarbonate/synthetic fluorohectorite nanocomposite.

magnified imageTEM bright field image of intercalated polycarbonate/synthetic fluorohectorite nanocomposite.


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