## Abstract **Summary:** Via a batch process in an autoclave, foam processing of intercalated PC/clay nanocomposites, having different amounts of clay, has been conducted using supercritical CO~2~ as a foaming agent. The cellular structures obtained from various foaming temperature‐CO~2~ pressure r
Intercalated Polycarbonate/Clay Nanocomposites: Nanostructure Control and Foam Processing
✍ Scribed by Masaki Mitsunaga; Yasuhito Ito; Suprakas Sinha Ray; Masami Okamoto; Katsuhiko Hironaka
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 212 KB
- Volume
- 288
- Category
- Article
- ISSN
- 1438-7492
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✦ Synopsis
Abstract
Intercalated polycarbonate (PC)/clay nanocomposites (PCCN)s have been prepared successfully through the melt intercalation method in the presence of a compatibilizer. The internal structure and morphology of the PCCNs has been established by using wide‐angle X‐ray diffraction (WAXD) analyses and transmission electron microscopic (TEM) observations. The morphology of these nanocomposites and degradation of the PC matrix after nanocomposites preparation can be controlled by varying surfactants used for the modification of clay and compatibilizer. The intercalated PCCNs exhibited remarkable improvements of mechanical properties when compared with PC without clay. We also discuss foam processing of one representative PCCN using supercritical CO~2~ as a foaming agent.
TEM bright field image of intercalated polycarbonate/synthetic fluorohectorite nanocomposite.
magnified imageTEM bright field image of intercalated polycarbonate/synthetic fluorohectorite nanocomposite.
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