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Interactive Surface Chemistry of CO 2 and NO 2 on Metal Oxide Surfaces: Competition for Catalytic Adsorption Sites and Reactivity

✍ Scribed by Vovk, Evgeny I.; Turksoy, Abdurrahman; Bukhtiyarov, Valerii I.; Ozensoy, Emrah


Book ID
120011916
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
760 KB
Volume
117
Category
Article
ISSN
1932-7447

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Chemical reactivity of oxygen vacancies
✍ Elizabeth Florez; Patricio Fuentealba; Fanor MondragΓ³n πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 710 KB

Density functional theory was used to investigate the chemical reactivity of oxygen vacancies on the MgO surface towards CO 2 , NO 2 and metal atoms. The oxygen vacancies induce changes in the electronic structure of the MgO compared to that of the regular surface. The most common surface defects ca