Interactions of polystyrene with n-alkanes in benzene solution
β Scribed by Issa A. Katime; Jose R. Quintana; Luis C. Cesteros
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 242 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0014-3057
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β¦ Synopsis
A~tract--Preferential and total sorption of polystyrene in benzene/n-alkane (C6, C7, C12 and C16) binary mixtures as a function of binary mixture composition have been studied by viscometry and laser light scattering. We have found, for high contents of n-alkane in the binary mixture, that benzene is always the liquid that solvates the polystyrene. This behaviour has been explained by taking into account that this binary mixture behaves similarly to a solvent/precipitant system. Also, we have found remarkable differences between the intra-and inter-molecular interactions of the system, due probably to solvation phenomena.
π SIMILAR VOLUMES
## Abstract Gasβliquid chromatography is used to study the thermodynamic interactions between polystyrene and __n__βalkanes (C~6~βC~10~). Polystyrene is used as a stationary phase with __n__βalkanes as the probe molecules. Retention times and specific retention volumes are measured over the tempera
Benzene solutions of purified egg leothln, with small amounts of water added, have been examined by 60 MHz and 100 MHz NMR spectroscopy, infrared spectrophotometry and phase contrast microscopy The transverse relaxation times of the water, N-methyl and O-H protons are dependent on water concentratio