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Interactions of plasminogen and fibrinogen with model silica glass surfaces: Adsorption from plasma and enzymatic activity studies

✍ Scribed by Woodhouse, K. A. ;Weitz, J. I. ;Brash, J. L.


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
920 KB
Volume
28
Category
Article
ISSN
0021-9304

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✦ Synopsis


The adsorption of fibrinogen and plasminogen from plasma to silica glass, sulfonated silica glass, and lysinederivatized silica glass has been investigated. The data indicate that the sulfonated material has a high affinity for both fibrinogen and plasminogen, but that the ratio of plasminogen to fibrinogen is greater on the lysinederivatized surface. The adsorption data also suggest plasminogen as a possible contributor to the fibrinogen Vroman effect, whereby initially adsorbed fibrinogen is displaced from the surface. The plasmin activity of plasminogen adsorbed to the lysine-derivatized silica glass and its sulfonated precursor was assessed by both a chromogenic substrate assay and a radioimmunoassay for the plasmin cleavage product of fibrinogen, the BP 1-42 peptide. The data indicate that 1) the adsorbed plasminogen is not inherently plasmin-like; 2) the enzymatic activity associated with the bound plasminogen is significantly enhanced on both surfaces in the presence of