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Interactions of Heteroaromatic Compounds with Nucleic Acids : 1. The Influence of Heteroatoms and Polarizability on the Base Specificity of Intercalating Ligands

✍ Scribed by Werner MÜLLER; Donald M. CROTHERS

Book ID
115114997
Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
942 KB
Volume
54
Category
Article
ISSN
1432-1327

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Influence of inductive effects and polar
Influence of inductive effects and polarizability on the acid-base properties of alkyl compounds. Inversion of the alcohol acidity scale
✍ J. Catalán 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 545 KB

The inductive effects and polarizability of a series of 17 alkyl substituents were evaluated in theoretical terms from ab initio calculations for acid-base processes involving the corresponding alkanols. The effects allow one to account for general acid-base processes, both in the gas phase and in s