Interactions of cobalt chloride with saccharose in aqueous solutions at 298.15 K

✍ Scribed by Ana C.F. Ribeiro; Artur J.M. Valente; Damien O. Costa; Susana M.N. Simões; Rui F.P. Pereira; Victor M.M. Lobo; Miguel A. Esteso

• Publisher: Elsevier Science
• Year: 2010
• Tongue: English
• Weight: 170 KB
• Volume: 55
• Category: Article
• ISSN: 0013-4686
• DOI: 10.1016/j.electacta.2010.02.090

✦ Synopsis

Mutual diffusion coefficients (interdiffusion coefficients) and molar electrical conductivities have been measured for cobalt chloride aqueous solutions in the absence and the presence of saccharose at different concentrations (from 0.01 to 0.3 mol dm -3 ) and 298.15 K. The diffusion coefficients were measured by using the conductimetric method. For these aqueous solutions, limiting molar conductivity values have been calculated. The value of 0 (Co 2+ ) = 105.36 × 10 -4 S m 2 mol -1 , obtained at 298.15 K in pure water solution, agrees well with that reported in the literature. The Nernst diffusion coefficient values derived from diffusion (1.301 × 10 -9 m 2 s -1 ) and from conductance (1.295 × 10 -9 m 2 s -1 ) are also in good agreement.

The dependence of diffusion coefficients and electrical conductivity of CoCl 2 on the concentration of saccharose is discussed by considering the effect of the carbohydrate on the electrolyte dehydration, as well as on the ion-pairs and complexes (CoCl 2 -saccharose and ions-saccharose) formation.