Interactions of C60 with organic molecules in solvate crystals studied by infrared spectroscopy

✍ Scribed by R. Świetlik; P. Byszewski; E. Kowalska

• Publisher: Elsevier Science
• Year: 1996
• Tongue: English
• Weight: 400 KB
• Volume: 254
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(96)00308-9

✦ Synopsis

Infrared absorption spectra (400-4000 cm -1) of C60 solvate crystals grown in benzene, toluene, chlorobenzene, decalin and n-decane have been measured in the temperature range 90-300 K. Chemical reactions of C6o with decalin and n-decane are observed. Interactions between C6o and solvent molecules have an influence on the infrared bands assigned to the C-H stretching vibrations. Solvent effects are also observed in the temperature dependence of the C60 infrared bands.