Interactions between Silica Colloids with Magnetite Cores: Diffusion, Sedimentation and Light Scattering
✍ Scribed by Liesbeth N. Donselaar; Albert P. Philipse
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 494 KB
- Volume
- 212
- Category
- Article
- ISSN
- 0021-9797
No coin nor oath required. For personal study only.
✦ Synopsis
The magnetic and Van der Waals attraction between uncharged silica spheres with a magnetic core has been studied using sedimentation and static and dynamic light scattering techniques. Specifically the effect of the interactions on the concentration dependence of the sedimentation velocity, diffusion, and the apparent radius of gyration was investigated. It was found experimentally that the concentration dependence is decreased significantly as a result of the Van der Waals and magnetic attractions and even may change sign in comparison to the hard-sphere case. Calculations of the (linear) concentration dependence for weak interactions predict this decrease and also indicate that for the silica-magnetite particles the second virial coefficient passes a maximum with increasing silica layer thickness.