Interactions between molecules in the neighborhood of a long linear molecule
β Scribed by John E. Krizan; Brian F. Lloyd
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 306 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
The thirdβorder interaction between two nonpolar molecules due to the instantaneous induced dipole effect of an infinitely long linear molecule is assessed following arguments similar to earlier research on threeβbody effects. It is found that an attractive force favors small polar angles in approach to the linear molecule; such behavior could be of interest to processes such as those involved in replication of DNA.
π SIMILAR VOLUMES
## Abstract Presenting a relatively simple __ab initio__ method to calculate full van der Waals interaction potentials between molecules, we give rules for the optimization of basis functions which permit the reliable evaluation of second order long range interactions. Closed expressions for the lo
The cxclwngc dlspcrsmn energy for the Incar HF dlmer is shown to quench =alO% of the drspcrsmn term an the regmn of the munmum. Slmphficd formuhc for cvaluatlon of the c\ch;lngc dlspcrslon effect arc tested.