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Interactions between Functional Groups. Part II. Structure of the 2-Dimethylaminobenzenediazonium Cation: Retention of Planarity Despite Excessive Steric Crowding

✍ Scribed by John D. Wallis; Jack D. Dunitz


Publisher
John Wiley and Sons
Year
1984
Tongue
German
Weight
270 KB
Volume
67
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The crystal structure of 2‐dimethylaminobenzenediazonium tetrafluoroborate has been determined at 183 K by X‐ray diffraction. The cation is very nearly planar, the strong steric interaction between the ortho‐groups being diminished by in‐plane angular distoritions.