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Interaction of Triphenyltin Hydride and Rhodium. Structure of [Rh(NCBPh 3 )(H)(SnPh 3 )(PPh 3 ) 2 ] and NMR ( 1 H, 15 N, 31 P, 103 Rh, 119 Sn) Study of Pyridine-Containing Derivatives

✍ Scribed by Carlton, Laurence; Weber, Rosemarie; Levendis, Demetrius C.

Book ID
126075489
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
130 KB
Volume
37
Category
Article
ISSN
0020-1669

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📜 SIMILAR VOLUMES

Rhodium-103 NMR of [Rh(X)(PPh3)3] [X = C
Rhodium-103 NMR of [Rh(X)(PPh3)3] [X = Cl, N3, NCO, NCS, N(CN)2, NCBPh3, CNBPh3, CN] and derivatives containing CO, isocyanide, pyridine, H2 and O2. Ligand, solvent and temperature effects
✍ Laurence Carlton 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB

## Abstract Rhodium‐103 chemical shifts are reported for 62 compounds, namely [Rh(X)(PPh~3~)~3~] [X = Cl, N~3~, NCO, NCS, N(CN)~2~, NCBPh~3~, CNBPh~3~, CN] and derivatives formed by replacement of a phosphine by CO, xylyl isocyanide (XNC) and pyridine and/or by oxidative addition of H~2~ or O~2~ to