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Interaction of the stable radical 2,2,6,6-tetramethylpiperidone-4-oxy-1 with acids

โœ Scribed by G. A. Abakumov; V. D. Tikhonov

Book ID
112433306
Publisher
Springer
Year
1969
Tongue
English
Weight
378 KB
Volume
18
Category
Article
ISSN
1573-9171

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The reaction of acyl peroxides with 2,2,
The reaction of acyl peroxides with 2,2,6,6-tetramethylpiperidinyl-1-oxy
โœ Graeme Moad; Ezio Rizzardo; David H. Solomon ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 233 KB

Benzoyl and lauroyl peroxides undergo induced decomposition by 2,2,6,6\_tetramethylpiperidinyl-1-oxy to form acyloxy radicals and carboxylic acid in equimolar amounts. Formation of the carboxylic acid does not involve free acyloxy radicals. In connection with studies of the interaction of vinyl mon