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Interaction of radiation-generated radicals with myoglobin in aqueous solution—IV. Mechanism of interaction of hydroxyl radicals with oxymyoglobin

✍ Scribed by Kevin D. Whitburn; Morton Z. Hoffman


Publisher
Elsevier Science
Year
1984
Weight
616 KB
Volume
24
Category
Article
ISSN
0146-5724

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## Abstract The reactions of methyl and methylperoxyl radicals derived from dimethyl sulfoxide (DMSO) with hydrogen peroxide, peroxymonocarbonate (HCO~4~^−^), and persulfate were studied. The major reaction observed for the hydroperoxides was the abstraction of the hydrogen atom by the radicals. Th