Interaction of nitrogen bases with some platinum(II) and palladium(II) complexes—usual and unusual features
✍ Scribed by Pradyot Banerjee
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 103 KB
- Volume
- 190-192
- Category
- Article
- ISSN
- 0010-8545
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✦ Synopsis
This short review describes the kinetic interaction of several platinum(II) and palladium(II) complexes with various nitrogen bases. The reactions have been categorized with the type of metal complexes. The reaction patterns of amine and ammine, pyridine-2-carboxylate, pyridine-2,6-dicarboxylate and pyridoxine complexes with the above metal ions have been discussed. Some unusual features in the above reactions have been noted.
📜 SIMILAR VOLUMES
The syntheses of [Pt(adenine)X,] \*2H,O (X = Cl, I), [Pt(adenosine)Iz] .2H,O, [Pt(guanosine)Jz] , [Pt-(guanine)Iz] and [Pt(cytosine)Iz] are reported. Infrared, electronic and proton n.m.r. spectra have been used to assign coordination numbers, denticity and binding sites of the ligands.
Cyclic voltammetry and spectroelectrochemistry studies are reported for the tetramethyl- tetrapyridinoporphyrazine complexes N,N′,N″,N‴-tetramethyltetra-2,3-pyridinoporphyrazine palladium(II) (1a), N,N′,N″,N‴-tetramethyltetra-3,4-pyridinoporphyrazine palladium(II) (1b), N,N′,N″,N‴-tetramethyltetra-2
2.2.3 Reactions of Pro-Gly-Ala-His and His-Pro-Gly-Ala-His with [Pd(en)(D 2 O) 2 ] 2 + and cis-[Pt(NH 3 )(D 2 O) 2 ] 2 + .