Interaction of [Mo6Cl14]2−with H2Se: Selective Preparation of [Mo6SeCl13]3−
✍ Scribed by Pavel A. Abramov; Maxim N. Sokolov; Alexandr V. Virovets; Eugenia V. Peresypkina; Cristian Vicent; Vladimir P. Fedin
- Book ID
- 106406419
- Publisher
- Springer
- Year
- 2008
- Tongue
- English
- Weight
- 266 KB
- Volume
- 20
- Category
- Article
- ISSN
- 1040-7278
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The reactivity of Mo and Mo~2~ with ammonia, ethene, and propene molecules has been investigated by using Density Functional Theory. Different gradient‐corrected and hybrid exchange‐correlation functionals have been employed. Coordination modes, binding energies, geometrical structures,
NH 4 ) 2 [Mo 6 Cl 14 ] ´H2 O (1) was prepared from reactions of MoCl 2 in ethanol with aqueous NH 4 Cl solution. It crystallizes in the monoclinic space group I2/a (no. 15), Z = 4 with a = 912.3(1), b = 1491.2(2), c = 1724.8(2) pm, b = 92.25(1)°; R1 = 0.023 (based on F values) and wR2 = 0.059 (based