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Interaction of methylal and methylal-d6 with electron acceptors

✍ Scribed by K.K. Kalninsh; V.N. Zgonnik; N.S. Dmitrieva; N.I. Nikolaev

Book ID
113373201
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
468 KB
Volume
29
Category
Article
ISSN
1386-1425

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✍ Žagar, Cyrill ;Scharf, Hans-Dieter 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 534 KB

## Abstract Methyl 2‐__O__‐benzyl‐6‐deoxy‐3‐__C__‐methyl‐α‐D‐mannopyranoside (2) was synthesized in ten steps by starting from the readily available methyl 2,3‐anhydro‐4,6‐__O__‐benzylidene‐α‐D‐allo‐pyranoside (3). The key step was the stereoselective __cis__‐hydroxylation (cat. osmium(VIII) oxide)