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Interaction of Hydronium Ion with Dibenzo-18-crown-6: NMR, IR, and Theoretical Study

✍ Scribed by Kříž, Jaroslav; Dybal, Jiří; Makrlík, Emanuel; Budka, Jan


Book ID
111890766
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
233 KB
Volume
112
Category
Article
ISSN
1089-5639

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Interaction of hydrated protons (HPs) with dibenzo-24-crown-8 (DBC in nitrobenzene-d 5 was studied by 1 H and 13 C NMR under assistance of ab initio-density functional theory (DFT) quantum calculations. HPs were afforded by hydrogen bis(1,2-dicarbollyl) cobaltate (HDCC) with 3.5 M excess of H 2 O. T