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Interaction of C60 and C70 with aromatic amines in the ground and excited states. Evindence for fullerene—benzene interaction in the ground state

✍ Scribed by Ram Seshadri; C.N.R. Rao; H. Pal; T. Mukherjee; J.P. Mittal

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
330 KB
Volume
205
Category
Article
ISSN
0009-2614

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✦ Synopsis

While CW interacts with aromatic amines such as dimethylaniline in the ground state, C,,, does not. Fluorescence spectroscopic studies, including lifetime measurements, show the formation of exciplexes of both Ca and Cm with arpmatic amines in nonaromatic solvents such as methylcyclohexane. Exciplexes are however not formed in benzene solvent, due to K--X interaction between benzene and the fidlerene. Based on spectroscopic absorption measurements, it is shown that both C, and CT0 do indeed interact with benzene in the ground state.

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