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Interaction of alkali metals with unsaturated heterocyclic compounds. The reductive metalation of 3-phenylcinnoline

✍ Scribed by Kaban, Seniz; Smith, James G.

Book ID
126469367
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
499 KB
Volume
2
Category
Article
ISSN
0276-7333

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πŸ“œ SIMILAR VOLUMES

Interaction of alkali metals with unsatu
Interaction of alkali metals with unsaturated heterocyclic compounds. The reductive metallation of 2,3,5,6-tetraphenylpyrazine and the synthesis of 1,2-dihydro-1,4-diazine derivatives
✍ Şeniz Kaban; NΓΌket Γ–cal πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 458 KB

## Abstract Treatment of 2,3,5,6‐tetraphenylpyrazine (1) with sodium in tetrahydrofuran effected the formation of monomeric dianion 2. The chemical behaviour of this new disodium adduct was characterized by a variety of reagents. Generally, the protonation (water), alkylation (methyl iodide and ben