Interaction of 2-Aminoindoles with Tetracyanoethylene. Part 2. 3-Dicyanomethylene-2-iminoindolines.
β Scribed by A. V. Sadovoy; G. A. Golubeva
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 16 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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Reaction of (Z)-[6]paracycloph-3-ene (2) with tetracyanoethylene (TCNE) gave a [2 + 21 cycloadduct (4, which represents the first example of thermal [ 2 + 2 ] cycloaddition of a benzene derivative under mild conditions. The structure of 4 was confirmed by x-ray crystallographic analysis. Semi-empiri
## Abstract The interaction of __N__β__tert__βbutylaziridine (TBA) with the strong Οβelectron acceptor tetracyanoethylene (TCNE) was investigated, which results in ringβopening polymerization of the aziridine. Chargeβtransfer complex formation between TBA and TCNE was proved by means of UV/VIS spec
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