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Interaction between surfaces with adsorbed polymers: poor solvents

โœ Scribed by Klein, J.; Pincus, Philip


Book ID
124090671
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
790 KB
Volume
15
Category
Article
ISSN
0024-9297

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## Abstract **Summary:** We consider the shape of strongly adsorbed polymer chains in poor solvents. Using both SCF theory and Monte Carlo simulations, we find these chains undergo an instability which is driven, surprisingly, by polymer entropy. This instability occurs above some critical grafting