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Interaction between phosphorus pentafluoride and phosphorus trifluoride and trialkyl phosphites

✍ Scribed by Brown, D. H.; Crosbie, K. D.; Fraser, G. W.; Sharp, D. W. A.

Book ID
121199175
Publisher
The Royal Society of Chemistry
Year
1969
Weight
588 KB
Category
Article
ISSN
0022-4944

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## Abstract The reaction between dialkyl acetylenedicarboxylates and NH heterocyclic compounds in the presence of trialkyl phosphite leads to stable phosphorus ylide derivatives in good yields. The x‐ray crystallographic data and theoretical study show that there is a resonance between two bonds of