The kinetics of the reaction CH,+OH (+M)dCH,OH (+M) was studied at room temperature by pulse radiolysis of SF,/ CHJH# mixtures. The methyl radical decay was followed by monitoring the UV absorption signals at 216.4 nm. A pressure dependence of k, was observed with values ranging from (5.8 kO.3) x 10
Interaction between methyl and hydroxyl radicals: a theoretical study
β Scribed by Antonius Indarto
- Publisher
- Springer Netherlands
- Year
- 2010
- Tongue
- English
- Weight
- 378 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0922-6168
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The reaction of CH3 with OH has been studied near 1200 K and 1 atmosphere pressure in shock tube experiments in which UV absorption was used to monitor [OH]. A rate coefficient of (1.1 ? 0.3) x 1013 cm3/mol-s was measured for removal of OH by CH3. This measured value is compared with previous experi
Ab initio molecular orbital theory and density functional theory calculations have been carried out on the reactions of the trifluoromethyl radical with the hydroxyl and the hydrogen radicals. These reactions are key reactions that underlie a new fire extinguishing mechanism of non-bromine-containin
## Abstract We report a theoretical study on seven radical hydrogen bond complexes between synβHCOOH and OH and eight radical hydrogen bond complexes between antiβHCOOH and OH, that have been carried out by using the B3βLYP, MP2, QCISD, and CCSD(T) theoretical approaches with the 6β311+G(2df,2p) ba