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Interaction between metallic gold and support and its influence on catalysis

✍ Scribed by Yang, Xuzhuang ;Shen, Yuenian ;Wang, Donghui ;Sun, Yongan


Publisher
Springer
Year
2008
Tongue
English
Weight
273 KB
Volume
95
Category
Article
ISSN
0133-1736

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There is no bonding between Au and S atoms coadsorbed on top of Ru (000 1) . Au compresses S into small islands of high local coverage, causing dramatic changes in the kinetics of sulfur desorption. The compression reduces the adsorption energy of sulfur on Ru(0001 ), favoring the desorption of Sz i