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Interaction between ammonium heptamolybdate and NH4ZSM-5 zeolite: the location of Mo species and the acidity of Mo/HZSM-5

✍ Scribed by Yide Xu; Yuying Shu; Shetian Liu; Jiasheng Huang; Xiexian Guo


Book ID
112412768
Publisher
Springer US
Year
1995
Tongue
English
Weight
565 KB
Volume
35
Category
Article
ISSN
1011-372X

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Computational study of the properties an
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Four different cluster models of Mo(VI) methylidene centres in the HZSM-5 framework are investigated with DFT. The positive charge on the MoO(CH 2 ) fragment is higher for the Mo centre with two Al atoms in its vicinity, compared to the models with only one Al site. The activity of two selected Mo c