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Interaction and vibrations of CN− chemisorbed on CU(100):theoretical studies

✍ Scribed by K. Hermann; W. Möller; P.S. Baugs


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
601 KB
Volume
39
Category
Article
ISSN
0368-2048

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Two major contributions to the shift of the C-O stretch vibrational frequency between free CO and chemisorbed CO/C\*:(lOO) are identified. The overlap and consequent repulsion between the CO and metal orbit& leads to an increase in the frequency. The metal charge donation and dative bonding to CO 2-