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Inter-flavin electron transfer in the ground state in the absence of external electron donors and acceptors

✍ Scribed by Humphrey I.X. Mager; Shiao-Chun Tu

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
319 KB
Volume
37
Category
Article
ISSN
0040-4039

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## Abstract Oxetane is a potential intermediate that is enzymatically formed during the repair of (6–4) DNA lesions by special repair enzymes (6–4 DNA photolyases). These enzymes use a reduced and deprotonated flavin to cleave the oxetane by single electron donation. Herein we report synthesis of D