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Inter- and intramolecular hydroacylation of alkenes employing a bifunctional catalyst system

✍ Scribed by Vautravers, Nicolas R.; Regent, Damien D.; Breit, Bernhard

Book ID
120011963
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
682 KB
Volume
47
Category
Article
ISSN
1359-7345

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Iodo-(5,10,15,20-tetrakis(1,2,3,4,5,6,7,8-octahydro-1,4:5,8-dimethanoanthracen-9-yl)porphyrinatorhodium(III), designated as [Rh(P\*)(I)], was prepared and its catalytic activity in the asymmetric cyclopropanation of alkenes with ethyl diazoacetate (EDA) was examined. High catalyst turnovers (TON >10