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Intensity of IR spectral bands, intramolecular interactions, and conformations of aryl chloromethyl ethers

✍ Scribed by V. L. Furer; A. A. Bredikhin; V. L. Polushina; A. M. Salikhova; A. N. Vereshchagin


Book ID
112445084
Publisher
Springer
Year
1986
Tongue
English
Weight
377 KB
Volume
35
Category
Article
ISSN
1573-9171

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Conformations of highly hindered aryl et
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## Abstract The PMR spectrum of 2‐bromo‐4,6‐dinitrophenyl 2′‐naphthyl ether (**1**) is consistent with the preferential adoption of a twist conformation (**1a**) in which the 6‐nitro group and the 1′‐hydrogen are located __endo__ to the ether link. This preference is explained by the formation of a