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Intensification of catalytic olefin hydroformylation in CO2-expanded media

✍ Scribed by Hong Jin; Bala Subramaniam; Anindya Ghosh; Jon Tunge


Publisher
American Institute of Chemical Engineers
Year
2006
Tongue
English
Weight
138 KB
Volume
52
Category
Article
ISSN
0001-1541

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An important step forward in the search for catalytically active polynuclear metal complexes has been made by George G. Stanley's group: The bimetallic complex cations r~c-[Rh,(nbd),L]~+ l r and rne~o-[Rh,(nbd),L]~+ l m (nbd = norbornadiene) which were isolated as tetrafluoroborates (Scheme l),[l1 w