Integrated electronics head further into the third dimension: Electronic properties

The crystal structures and electronic pr

The crystal structures and electronic properties of three new [Cu(bipy)2(ONO)][Y] complexes. The structural pathway of the [Cu(bipy)2(ONO)][Y] series of complexes. Further insights into the Pseudo Jahn–Teller model

✍ Brian Murphy; George Roberts; Suresh Tyagi; Brian J Hathaway 📂 Article 📅 2004 🏛 Elsevier Science 🌐 English ⚖ 295 KB

The crystal structures of three new [Cu(bipy) , 2, and [I] 2 , 3, have been determined at room temperature by single crystal X-ray analysis. All three complexes involve a CuN 4 O 2 chromophore, with an asymmetric cis-distorted octahedral (CDO) stereochemistry. The stereochemistries of 1, 2 and 3, a