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Insulator-to-metal transition in doped polyacetylene

✍ Scribed by M.J. Rice; J. Timonen


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
207 KB
Volume
73
Category
Article
ISSN
0375-9601

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A local model is set up for the conductivity in alkali-doped polyacetylene Ε½ . PA based on results of ab initio and semiempirical calculations. At low doping levels, Ε½ . solitons and polarons appear naturally in the nondegenerate ground state. Alkali atoms donate their valence electrons to neutral s