✦ LIBER ✦

Instability constants of platinum complexes

✍ Scribed by A. A. Grinberg; G. A. Shagisultanova; M. I. Gel'fman

Book ID: 112419168
Publisher: Springer
Year: 1963
Tongue: English
Weight: 745 KB
Volume: 12
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00843935

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The 31P NMR spectra of complexes of the type Pt(SeSN2)(PR3)2 and Pt(Se2N2)(PR3)2 display trans 2J(77Se-31P) couplings of ca. 30-80 Hz, with no corresponding cis coupling; in contrast Pt(TeSN2)(PMe2Ph)2 has both trans and cis 2J(125Te-31P) couplings of 146 Hz and 103 H z respectively. The 31P spectra

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