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Insights into the Origin of High Activity and Stability of Catalysts Derived from Bulky, Electron-Rich Monophosphinobiaryl Ligands in the Pd-Catalyzed C−N Bond Formation

✍ Scribed by Strieter, Eric R.; Blackmond, Donna G.; Buchwald, Stephen L.

Book ID: 111644714
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 120 KB
Volume: 125
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja037932y

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One of the most general catalyst systems, in terms of their efficacy in CÀC, CÀN, and CÀO bond-forming reactions, are those based on the bulky, electron-rich monophosphinobiaryl ligands (Scheme 1). [1] First introduced in 1998, the Pd 0 catalyst based on 1 a demonstrated exceptionally high activity,