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Insights into the Origin of High Activity and Stability of Catalysts Derived from Bulky, Electron-Rich Monophosphinobiaryl Ligands in the Pd-Catalyzed C−N Bond Formation

✍ Scribed by Strieter, Eric R.; Blackmond, Donna G.; Buchwald, Stephen L.


Book ID
111644714
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
120 KB
Volume
125
Category
Article
ISSN
0002-7863

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Evidence for the Formation and Structure
✍ Eric R. Strieter; Stephen L. Buchwald 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 2 views

One of the most general catalyst systems, in terms of their efficacy in CÀC, CÀN, and CÀO bond-forming reactions, are those based on the bulky, electron-rich monophosphinobiaryl ligands (Scheme 1). [1] First introduced in 1998, the Pd 0 catalyst based on 1 a demonstrated exceptionally high activity,