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Insights into the Mechanism of Flavoprotein-Catalyzed Amine Oxidation from Nitrogen Isotope Effects on the Reaction of N- Methyltryptophan Oxidase †

✍ Scribed by Ralph, Erik C.; Hirschi, Jennifer S.; Anderson, Mark A.; Cleland, W. Wallace; Singleton, Daniel A.; Fitzpatrick, Paul F.

Book ID
126429275
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
113 KB
Volume
46
Category
Article
ISSN
0006-2960

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Insights into the mechanisms of flavopro
Insights into the mechanisms of flavoprotein oxidases from kinetic isotope effects
✍ Paul F. Fitzpatrick 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 French ⚖ 167 KB

## Abstract Deuterium, solvent, and ^15^N kinetic isotope effects have been used to probe the mechanisms by which flavoproteins oxidize carbon–oxygen and carbon–nitrogen bonds in amines, hydroxy acids, and alcohols. For the amine oxidases D‐amino acid oxidase, __N__‐methyltryptophan oxidase, and tr